PPC stands for Pay per Click. When you go to a search engine like Yahoo or Google, and search for something, the results come back in the middle of the page. Along the top of the page and on the right side of the page you'll see "sponsored links". These are PPC advertisements on the other hand ppv which stands for pay per view is a cable television service by which customers can order access to a particular broadcast for a fee.
Both of them a very huge difference between them.

it's a very broad question.
You can make millions with everything.

I would like to suggest ppv, it is the best way to earn $$$ due to lot of visitors. If you have a website and you can use ppv , then you will get good sum of money.

LOL. Both are using two different media.

PPC- pay per click - it is one type of advertisement in online platform. You will get paid when some one click your advertisement.
PPV- pay per view - You will get paid for every views of your advertisement.

There were number of tutorials and videos on web. Please make a simple search about your queries.